Iridium(I)– and Rhodium(I)–Olefin Complexes Containing an α-Diimine Supporting Ligand
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DOI: 10.1021/acs.organomet.2c00036
Abstract: Iridium(I) complexes of the type IrX(olefin)(α-diimine) (α-diimine = 1,4-bis(2,6-xylyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene; X = Cl, I, Me, O2CCF3; olefin = ethylene, cyclooctene (COE)) were synthesized from the readily available precursor [IrCl(COE)2]2. These complexes display unusual 1H NMR spectra… read more here.
Keywords: olefin complexes; diimine; iridium rhodium; rhodium ... See more keywords