Dual Effects of Cyclopentadienyl Ligands on Rh(III)-Catalyzed Dehydrogenative Arylation of Electron-Rich Alkenes
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DOI: 10.1021/acscatal.8b01753
Abstract: Despite extensive research on transition metal-catalyzed Fujiwara–Moritani type C–H olefinations, the alkenes used in these transformations are still mainly limited to active acrylate esters and styrenes. Selective aryl C–H olefination with electron-rich alkenes is recognized… read more here.
Keywords: rich alkenes; electron rich; dehydrogenative arylation; electron ... See more keywords
A Giese reaction for electron-rich alkenes†‡
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DOI: 10.1039/d0sc06341j
Abstract: A general method for the hydroalkylation of electron-rich terminal and non-terminal alkenes such as enol esters, alkenyl sulfides, enol ethers, silyl enol ethers, enamides and enecarbamates has been developed. The reactions are carried out at… read more here.
Keywords: rich alkenes; electron rich; reaction electron; giese reaction ... See more keywords