Electrochemical Difluoromethylation of Electron-Rich Olefins.
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DOI: 10.1021/acs.orglett.3c00310
Abstract: The electrochemical difluoromethylation of electron-rich olefins (enamides and styrene derivatives) is disclosed. The addition of the electrogenerated difluoromethyl radical from the corresponding sodium sulfinate (i.e., HCF2SO2Na) to enamides and styrenes in an undivided cell allowed… read more here.
Keywords: difluoromethylation electron; electrochemical difluoromethylation; electron rich; rich olefins ... See more keywords
Iron-Catalyzed Meerwein Carbooxygenation of Electron-Rich Olefins: Studies with Styrenes, Vinyl Pyrrolidinone, and Vinyl Oxazolidinone
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DOI: 10.1021/acsomega.9b03046
Abstract: The arylative oxygenation of the electron-rich olefins styrene, α-methylstyrene, vinyl pyrrolidinone, and vinyl oxazolidinone was accomplished using arenediazonium salts and catalytic amounts of FeSO4 in an effective single electron transfer radical process. A broad range… read more here.
Keywords: electron rich; vinyl pyrrolidinone; vinyl; rich olefins ... See more keywords