Articles with "rieske oxygenase" as a keyword



Leveraging a Structural Blueprint to Rationally Engineer the Rieske Oxygenase TsaM.

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Published in 2023 at "Biochemistry"

DOI: 10.1021/acs.biochem.3c00150

Abstract: Rieske nonheme iron oxygenases use two metallocenters, a Rieske-type [2Fe-2S] cluster and a mononuclear iron center, to catalyze oxidation reactions on a broad range of substrates. These enzymes are widely used by microorganisms to degrade… read more here.

Keywords: structural blueprint; chemistry; tsam; rieske oxygenase ... See more keywords
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Rieske Oxygenase Catalyzed C–H Bond Functionalization Reactions in Chlorophyll b Biosynthesis

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Published in 2022 at "ACS Central Science"

DOI: 10.1021/acscentsci.2c00058

Abstract: Rieske oxygenases perform precise C–H bond functionalization reactions in anabolic and catabolic pathways. These reactions are typically characterized as monooxygenation or dioxygenation reactions, but other divergent reactions are also catalyzed by Rieske oxygenases. Chlorophyll(ide) a… read more here.

Keywords: rieske; bond functionalization; cao; rieske oxygenase ... See more keywords