Polyoxometalate-based inorganic-organic hybrids based on a half rigid N-heterocyclic carboxylate ligand: Syntheses, structures and properties
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DOI: 10.1016/j.molstruc.2020.128256
Abstract: Abstract Three new inorganic-organic hybrids constructed from a half rigid N-heterocyclic carboxylate ligand, K[Ag3(HL1)4](Mo8O26) (1), [Ag4(HL1)2(HL2)2(SiMo12O40)] (2) and (H3O)[Ag(L1)2]·2H2O (3) [HL1 = 1-(4-carboxylbenzyl)-3-(pyrazine-2-yl)pyrazole; HL2 = 3-(2-pyrazine)pyrazole], were hydrothermally synthesized and characterized. In compound 1, {K[β-Mo8O26]}n3n− chains fill in the… read more here.
Keywords: rigid heterocyclic; organic hybrids; carboxylate ligand; inorganic organic ... See more keywords