C(sp3)-H Ritter amination by excitation of in situ generated iodine(III)-BF3 complexes.
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DOI: 10.1039/d2cc03283j
Abstract: Visible light excitation of iodine(III)-BF3 complex enables the formation of carbocations from C(sp3)-H bonds. The complexes are generated catalytically from iodoarene, carboxylate ligand, the oxidizing agent Selectfluor, and the Lewis acid BF3. This modular catalytic… read more here.
Keywords: excitation; bf3; sp3 ritter; iodine iii ... See more keywords