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   Articles with "rocop" as a keyword



Alternating ring‐opening copolymerization of cyclic anhydrides and epoxides by zeolitic imidazolate framework‐67: A promising approach

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recommendations! Published in 2024 at "Applied Organometallic Chemistry"

DOI: 10.1002/aoc.7416

Abstract: The ring opening copolymerization (ROCOP) of epoxides and cyclic anhydrides is one of the most important ways to synthesize polyesters both in industrial and academic fields. Herein, the zeolitic imidazolate framework‐67 (ZIF‐67) was used as… read more here.

Keywords: opening copolymerization; rocop; copolymerization; ring opening ... See more keywords

Synergic Heterodinuclear Catalysts for the Ring-Opening Copolymerization (ROCOP) of Epoxides, Carbon Dioxide, and Anhydrides

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recommendations! Published in 2022 at "Accounts of Chemical Research"

DOI: 10.1021/acs.accounts.2c00197

Abstract: Conspectus The development of sustainable plastic materials is an essential target of chemistry in the 21st century. Key objectives toward this goal include utilizing sustainable monomers and the development of polymers that can be chemically… read more here.

Keywords: opening copolymerization; development; heterodinuclear catalysts; rocop ... See more keywords

Understanding the Effect of M(III) Choice in Heterodinuclear Polymerization Catalysts

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recommendations! Published in 2024 at "Inorganic Chemistry"

DOI: 10.1021/acs.inorgchem.4c04430

Abstract: The ring-opening copolymerization (ROCOP) of epoxides with CO2 or anhydrides is a promising strategy to produce sustainable polycarbonates and polyesters. Currently, most catalysts are reliant on scarce and expensive cobalt as the active center, while… read more here.

Keywords: catalyst; iii; rocop; polymerization ... See more keywords

Gateway to Sustainable Polymers via Catalytic ROCOP of CO2/COS Utilizing a Renewable Epoxide Monomer from Furfural Derivatives

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recommendations! Published in 2025 at "ACS Sustainable Chemistry & Engineering"

DOI: 10.1021/acssuschemeng.5c08323

Abstract: In recent years, there has been an increase in demand for a paradigm shift from fossil fuel-based feedstock to renewable feedstock for polymer synthesis due to the need for expanding the source of these materials… read more here.

Keywords: cos; rocop; co2; furfural derivatives ... See more keywords