Articles with "role catalytic" as a keyword



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Probing the Role of Catalytic Triad on the Cleavage between Intramolecular Chaperone and NK Mature Peptide.

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Published in 2021 at "Journal of agricultural and food chemistry"

DOI: 10.1021/acs.jafc.0c07238

Abstract: Many proteases require the assistance of an intramolecular chaperone (IMC) that is essential for protein folding. Subtilisin is produced as a precursor that requires its N-terminal propeptide to act as an IMC to chaperone the… read more here.

Keywords: subtilisin domain; cleavage; intramolecular chaperone; role catalytic ... See more keywords
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A Role for Pd(IV) in Catalytic Enantioselective C-H Functionalization with Monoprotected Amino Acid Ligands under Mild Conditions.

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Published in 2017 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.7b03716

Abstract: Kinetic and mechanistic studies of the desymmetrization of benzhydrylamine using Pd/monoprotected amino acid ligands (Pd/MPAA) via C-H functionalization with molecular iodine provide mechanistic insight into the rate-determining step and the oxidation state of Pd in… read more here.

Keywords: acid ligands; amino acid; monoprotected amino; role catalytic ... See more keywords