Role of σ,π-Digold(I) Alkyne Complexes in Reactions of Enynes
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DOI: 10.1021/acs.organomet.7b00668
Abstract: Gold(I) acetylide and σ,π-digold(I) alkyne complexes derived from one prototypical 1,6-enyne and from 7-ethynyl-1,3,5-cycloheptatriene have been prepared and structurally characterized. Their possible role in gold(I)-catalyzed cycloisomerizations has been studied by experiment and by DFT calculations.… read more here.
Keywords: role digold; alkyne complexes; digold alkyne; reactions enynes ... See more keywords