The role of solvent and neutral organophosphorus extractant structure in their organization and association
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Molecular Liquids"
DOI: 10.1016/j.molliq.2018.01.031
Abstract: Abstract The choice of organic solvent is known to impact metal ion partitioning in solvent extraction systems, although an understanding based on molecular interactions has been largely qualitative. To provide a more quantitative and molecular… read more here.
Keywords: volume; role solvent; diethyl ether; extractant solvent ... See more keywords
Triphenylphosphine Oxide Removal from Reactions: The Role of Solvent and Temperature
Sign Up to like & getrecommendations! Published in 2021 at "ACS Omega"
DOI: 10.1021/acsomega.1c01996
Abstract: Here, a large-scale feasible, chromatography-free process to purge triphenylphosphine oxide (TPPO) from the crude product of Mitsunobu and Wittig reactions has been developed. Divergence in physicochemical properties like polarity and solubility of TPPO against the… read more here.
Keywords: triphenylphosphine oxide; removal reactions; role solvent; oxide removal ... See more keywords