Mechanistic Studies on Ruthenium(II)-Catalyzed Base-Free Transfer Hydrogenation Triggered by Roll-Over Cyclometalation.
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DOI: 10.1002/cplu.201600526
Abstract: The synthesis of 2-substituted pyridine-pyrimidine ligands and their complexation with arene ruthenium(II) chloride moieties is reported. Depending on the electronic and steric influences of the ligand, the catalysts undergo CH activation by roll-over cyclometalation. This… read more here.
Keywords: cyclometalation; base free; transfer hydrogenation; roll cyclometalation ... See more keywords