Catalytic Asymmetric Roskamp Reaction of Silyl Diazoalkane: Synthesis of Enantioenriched α-Silyl Ketone.
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DOI: 10.1021/acs.orglett.7b02928
Abstract: A catalytic enantioselective Roskamp reaction of silyl diazoalkane to synthesize a highly optically active α-silyl ketone from aldehydes is described. In the presence of a chiral oxazaborolidinium ion catalyst, the reaction provides α-chiral silyl ketones… read more here.
Keywords: reaction silyl; silyl; roskamp; roskamp reaction ... See more keywords