Methyl-rotation dynamics in metal-organic frameworks probed with terahertz spectroscopy.
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DOI: 10.1039/c8cc02650e
Abstract: In ZIF-8 and its cobalt analogue ZIF-67, the imidazolate methyl-groups, which point directly into the void space, have been shown to freely rotate - even down to cryogenic temperatures. Using a combination of experimental terahertz… read more here.
Keywords: methyl rotation; rotation dynamics; dynamics metal; metal organic ... See more keywords