Rotational spectroscopy and precise molecular structure of 1,2-dichlorobenzene
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Molecular Spectroscopy"
DOI: 10.1016/j.jms.2020.111380
Abstract: Abstract Supersonic expansion rotational spectroscopy at 4–18 GHz with rectangular pulse and chirp excitation was used to measure spectra of twelve isotopic species of 1,2-dichlorobenzene at conditions of completely resolved double chlorine hyperfine structure by using… read more here.
Keywords: molecular structure; rotational spectroscopy; precise molecular; spectroscopy ... See more keywords
Monitoring Chemical Reactions with Terahertz Rotational Spectroscopy
Sign Up to like & getrecommendations! Published in 2018 at "ACS Photonics"
DOI: 10.1021/acsphotonics.8b00342
Abstract: Rotational spectroscopy is introduced as a new in situ method for monitoring gas-phase reactants and products during chemical reactions. Exploiting its unambiguous molecular recognition specificity and extraordinary detection sensitivity, rotational spectroscopy at terahertz frequencies was… read more here.
Keywords: rotational spectroscopy; monitoring chemical; terahertz rotational; reactions terahertz ... See more keywords
Assessing the performance of rotational spectroscopy in chiral analysis
Sign Up to like & getrecommendations! Published in 2020 at "Chemical Science"
DOI: 10.1039/d0sc03752d
Abstract: The capabilities of rotational spectroscopy-based methods as tools to deliver accurate and precise chirality-sensitive information are still breaking ground, but their applicability in the challenging field of analytical chemistry is already clear. In this mini… read more here.
Keywords: chiral analysis; rotational spectroscopy; spectroscopy; assessing performance ... See more keywords
High-resolution rovibrational and rotational spectroscopy of singly deuterated cyclopropenyl cation, c-C3H2D+
Sign Up to like & getrecommendations! Published in 2023 at "Faraday Discussions"
DOI: 10.1039/d3fd00068k
Abstract: Applying a novel action spectroscopic technique in a 4 K cryogenic ion trap instrument, the molecule C3H2D+ has been investigated by high-resolution rovibrational and pure rotational spectroscopy for the first... read more here.
Keywords: spectroscopy; c3h2d; high resolution; rotational spectroscopy ... See more keywords
Rotational spectroscopy of the two conformers of 3-methylbutyronitrile (C_4H_9CN) between 2 and 400 GHz
Sign Up to like & getrecommendations! Published in 2018 at "Astronomy and Astrophysics"
DOI: 10.1051/0004-6361/201832994
Abstract: We present high-resolution rotational spectroscopy of the two conformers of 3-methylbutyronitrile (C_4H_9CN). Spectra were taken between 2 and 24 GHz by means of Fourier transform microwave spectroscopy. Spectra between 36 and 403 GHz were recorded… read more here.
Keywords: methylbutyronitrile 9cn; rotational spectroscopy; conformers methylbutyronitrile; spectroscopy ... See more keywords
Toward Accurate yet Effective Computations of Rotational Spectroscopy Parameters for Biomolecule Building Blocks
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28020913
Abstract: The interplay of high-resolution rotational spectroscopy and quantum-chemical computations plays an invaluable role in the investigation of biomolecule building blocks in the gas phase. However, quantum-chemical methods suffer from unfavorable scaling with the dimension of… read more here.
Keywords: spectroscopy parameters; toward accurate; spectroscopy; building blocks ... See more keywords