Synthesis of atomically precise single-crystalline Ru2-based coordination polymers.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt02233k
Abstract: Methods to incorporate kinetically inert metal nodes and highly basic ligands into single-crystalline metal-organic frameworks (MOFs) are scarce, which prevents synthesis and systematic variation of many potential heterogeneous catalyst materials. Here we demonstrate that metallopolymerization… read more here.
Keywords: precise single; atomically precise; coordination; single crystalline ... See more keywords
8-Hydroxyquinoline-modified ruthenium(II) polypyridyl complexes for JMJD inhibition and photodynamic antitumor therapy.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01765b
Abstract: As an ideal scaffold for metal ion chelation, 8-hydroxyquinoline (8HQ) can chelate different metal ions, such as Fe2+, Cu2+, Zn2+, etc. Here, by integrating 8HQ with a ruthenium(II) polypyridyl moiety, two Ru(II)-8HQ complexes (Ru1 and… read more here.
Keywords: antitumor; ruthenium polypyridyl; ru2; ru1 ru2 ... See more keywords
Contrasting Magnetism in Isovalent Layered LaSr3NiRuO4H4 and LaSrNiRuO4 due to Distinct Spin-Orbital States
Sign Up to like & getrecommendations! Published in 2019 at "Chinese Physics Letters"
DOI: 10.1088/0256-307x/36/7/077501
Abstract: The recently synthesized first 4d transition-metal oxide-hydride LaSr3NiRuO4H4 with the unusual high H:O ratio surprisingly displays no magnetic order down to 1.8 K. This is in sharp contrast to the similar unusual low-valent Ni+ -… read more here.
Keywords: spin orbital; magnetism; state; orbital states ... See more keywords