Visible Light Driven Bromide Oxidation and Ligand Substitution Photochemistry of a Ru Diimine Complex.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.8b00944
Abstract: The complex [Ru(deeb)(bpz)2]2+ (RuBPZ2+, deeb = 4,4'-diethylester-2,2'-bipyridine, bpz = 2,2'-bipyrazine) forms a single ion pair with bromide, [RuBPZ2+, Br-]+, with Keq = 8400 ± 200 M-1 in acetone. The RuBPZ2+ displayed photoluminescence (PL) at room… read more here.
Keywords: rubpz2; visible light; deeb bpz; rate constant ... See more keywords