Influence of highly basic phosphine ligand on the reactivity and hydrolysis of P4 and P4S3 supported by ruthenium fragments
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.01.005
Abstract: Abstract Substitution of PPh3 in [RuCp(PPh3)2Cl] with highly basic PMe3 gave a remarkable change in the reactivity towards P4 and unexpectedly only the bimetallic complex cation [{RuCp(PMe3)2}2(μ,η1:1-P4)]2+ (3) was formed which was characterized by NMR… read more here.
Keywords: ruthenium; rucp pme3; rucp; p4s3 ... See more keywords
Insights into the κ-P,N Coordination of 1,3,5-Triaza-7-phosphaadamantane and Derivatives: κ-P,N-Heterometallic Complexes and a 15N Nuclear Magnetic Resonance Survey
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.1c03831
Abstract: Complexes {[(PTA)2CpRu-μ-CN-1κC:2κ2N-RuCp(PTA)2-ZnCl3]}·2DMSO (13) {[ZnCl2(H2O)]-(PTA-1κP:2κ2N)(PTA)CpRu-μ-CN-1κC:2κ2N-RuCp(PTA)(PTA-1κP:2κ2N)-[ZnCl2(H2O)]}Cl (14), [RuCp(HdmoPTA)(PPh3)(PTA)](CF3SO3)2 (20), [RuCp(HdmoPTA)(HPTA)(PPh3)](CF3SO3)3 (21), and [RuCp(dmoPTA)(PPh3)(PTA)](CF3SO3) (22) were obtained and characterized, and their crystal structure together with that of the previously published complex 18 is reported. The behavior of the… read more here.
Keywords: magnetic resonance; 15n nuclear; nuclear magnetic; coordination ... See more keywords
Synthesis, structure, properties, and cytotoxicity of a (quinoline)RuCp+ complex.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt03484k
Abstract: A rare example of a structurally characterized metal quinoline complex was prepared using a non-covalent quinoline-based proteasome inhibitor (Quin1), and a related complex bearing an inactive quinoline ligand (Quin2) was also synthesized. The quinolines are… read more here.
Keywords: rpmi 8226; cytotoxicity; dmso; pf6 ... See more keywords