Syntheses of RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3 Containing Various Triarylphosphines and Their Use for Arylation of Sterically Congested Aromatic C–H Bonds
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DOI: 10.1021/acs.organomet.6b00540
Abstract: A series of ruthenium complexes, RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3, containing various triarylphosphines were synthesized. Screening of these complexes as catalysts for direct arylation of sterically congested ortho C–H bonds of aromatic ketones improved the yields of… read more here.
Keywords: containing various; par3 containing; ruh2 par3; arylation ... See more keywords