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Published in 2019 at "Chembiochem"
DOI: 10.1002/cbic.201900419
Abstract: There is a current surge of interest in the development of novel photosensitizers (PSs) for photodynamic therapy (PDT), as those currently approved are not completely ideal. Among the tested compounds, we have previously investigated the…
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Keywords:
photodynamic therapy;
ruii;
receptor;
ruii polypyridyl ... See more keywords
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Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.02.052
Abstract: Abstract The recent developments in the direction of metal chelation assisted diverse mode of functionalization of β-diketiminate (nacnac) led to the present deliberation of C(sp2)–H bond oxygenation of Ru-coordinated nacnac through small molecule (O2) activation.…
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Keywords:
ancillary ligand;
acac;
oxygenation;
ruii ... See more keywords
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Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00865
Abstract: This article deals with the development of the unprecedented redox-mediated heterometallic coordination polymer {[RuIII(acac)2(μ-bis-η1-N,η1-N-BTD)2AgI(ClO4)]ClO4}n (3) via the oxidation of the monomeric building block cis-[RuII(acac)2(η1-N-BTD)2] (1) by AgClO4 (BTD = exodentate 2,1,3-benzothiadiazole, acac = acetylacetonate). Monomeric…
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Keywords:
acac;
ruii;
water;
heterometallic coordination ... See more keywords
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Published in 2019 at "Chemical communications"
DOI: 10.1039/c9cc00206e
Abstract: A photoactive, hetero-metallic CoII/RuII-based metal-organic framework (MOF) with a large channel aperture, ca. 21 Å, is reported. The photophysical properties of the MOF are derived from the RuII nodes giving rise to emission centred at…
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Keywords:
coii;
mof large;
channel aperture;
ruii ... See more keywords
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Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt03825g
Abstract: The phosphine-substituted Ru(II) polypyridyl complex, [RuII-(tpy)(pqn)(MeCN)]2+ (RuP), was disclosed to be an efficient photocatalyst for the reduction of CO2 to CO with excellent selectivity. In this work, density functional calculations were performed to elucidate the…
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Keywords:
catalyst;
selectivity photocatalyzed;
mechanism selectivity;
reduction ... See more keywords
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Published in 2017 at "Australian Journal of Chemistry"
DOI: 10.1071/ch16577
Abstract: Crystal structure determination on the mixed ligand complex [Ru(tpy)(L1)](ClO4)2 (tpy = 2,2′:6′,2″-terpyridine; L1 = 4′-(ferrocenylmethylaminomethylphenyl)terpyridine) shows the ferrocenyl group to be located as remotely as possible from the RuII centre. This may explain the fact that emission from the…
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Keywords:
crystal structure;
terpyridine;
ruii;
heterometallic luminophore ... See more keywords
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Published in 2022 at "Acta Crystallographica Section E: Crystallographic Communications"
DOI: 10.1107/s2056989022004443
Abstract: The crystal structures of two RuII complexes bearing a tridentate polypyridine ligand and N-coordinating thiocyanato ligands at the axial or equatorial position are compared.
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Keywords:
ruii dnp;
comparison ruii;
ruii;
dnp complexes ... See more keywords