Articles with "ruii" as a keyword



Synthesis and Characterization of an Epidermal Growth Factor Receptor‐Selective RuII Polypyridyl–Nanobody Conjugate as a Photosensitizer for Photodynamic Therapy

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Published in 2019 at "Chembiochem"

DOI: 10.1002/cbic.201900419

Abstract: There is a current surge of interest in the development of novel photosensitizers (PSs) for photodynamic therapy (PDT), as those currently approved are not completely ideal. Among the tested compounds, we have previously investigated the… read more here.

Keywords: photodynamic therapy; ruii; receptor; ruii polypyridyl ... See more keywords
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Electronic impact of ancillary ligand on the oxygenation profile of ruthenium coordinated β-diketiminate

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Published in 2019 at "Polyhedron"

DOI: 10.1016/j.poly.2019.02.052

Abstract: Abstract The recent developments in the direction of metal chelation assisted diverse mode of functionalization of β-diketiminate (nacnac) led to the present deliberation of C(sp2)–H bond oxygenation of Ru-coordinated nacnac through small molecule (O2) activation.… read more here.

Keywords: ancillary ligand; acac; oxygenation; ruii ... See more keywords
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Ruthenium-Benzothiadiazole Building Block Derived Dynamic Heterometallic Ru-Ag Coordination Polymer and Its Enhanced Water-Splitting Feature.

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Published in 2021 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.1c00865

Abstract: This article deals with the development of the unprecedented redox-mediated heterometallic coordination polymer {[RuIII(acac)2(μ-bis-η1-N,η1-N-BTD)2AgI(ClO4)]ClO4}n (3) via the oxidation of the monomeric building block cis-[RuII(acac)2(η1-N-BTD)2] (1) by AgClO4 (BTD = exodentate 2,1,3-benzothiadiazole, acac = acetylacetonate). Monomeric… read more here.

Keywords: acac; ruii; water; heterometallic coordination ... See more keywords
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Light-harvesting, 3rd generation RuII/CoII MOF with a large, tubular channel aperture.

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Published in 2019 at "Chemical communications"

DOI: 10.1039/c9cc00206e

Abstract: A photoactive, hetero-metallic CoII/RuII-based metal-organic framework (MOF) with a large channel aperture, ca. 21 Å, is reported. The photophysical properties of the MOF are derived from the RuII nodes giving rise to emission centred at… read more here.

Keywords: coii; mof large; channel aperture; ruii ... See more keywords
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Mechanism and selectivity of photocatalyzed CO2 reduction by a function-integrated Ru catalyst.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d1dt03825g

Abstract: The phosphine-substituted Ru(II) polypyridyl complex, [RuII-(tpy)(pqn)(MeCN)]2+ (RuP), was disclosed to be an efficient photocatalyst for the reduction of CO2 to CO with excellent selectivity. In this work, density functional calculations were performed to elucidate the… read more here.

Keywords: catalyst; selectivity photocatalyzed; mechanism selectivity; reduction ... See more keywords
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Crystal Structure of a Heterometallic Luminophore: The RuII Complex of a Ferrocenyl-Terpyridine with a Flexible Linkage*

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Published in 2017 at "Australian Journal of Chemistry"

DOI: 10.1071/ch16577

Abstract: Crystal structure determination on the mixed ligand complex [Ru(tpy)(L1)](ClO4)2 (tpy = 2,2′:6′,2″-terpyridine; L1 = 4′-(ferrocenylmethylaminomethylphenyl)terpyridine) shows the ferrocenyl group to be located as remotely as possible from the RuII centre. This may explain the fact that emission from the… read more here.

Keywords: crystal structure; terpyridine; ruii; heterometallic luminophore ... See more keywords
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Isolation and structural comparison of RuII-dnp complexes [dnp = 2,6-bis(1,8-naphthyridin-2-yl)pyridine] with axially or equatorially coordinating NCS ligands

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Published in 2022 at "Acta Crystallographica Section E: Crystallographic Communications"

DOI: 10.1107/s2056989022004443

Abstract: The crystal structures of two RuII complexes bearing a tridentate polypyridine ligand and N-coordinating thiocyanato ligands at the axial or equatorial position are compared. read more here.

Keywords: ruii dnp; comparison ruii; ruii; dnp complexes ... See more keywords