Molecular and Electronic Structures of Ruthenium Complexes Containing an ONS-Coordinated Open-Shell π Radical and an Oxidative Aromatic Ring Cleavage Reaction.
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DOI: 10.1021/acs.inorgchem.6b02862
Abstract: The coordination chemistry of 2,4-di-tert-butyl-6-[(2-mercaptophenyl)amino]phenol (LONSH3), which was isolated as a diaryl disulfide form, (LONSH2)2, with a Ru ion is disclosed. It was established that the trianionic LONS3- is redox-noninnocent and undergoes oxidation to either… read more here.
Keywords: ruii lons; pph3; chemistry; reaction ... See more keywords