Cooperative Bond Activation Reactions with Ruthenium Carbene Complex PhSO2(Ph2PNSiMe3)C═Ru(p-cymene): Ru═C and N–Si Bond Reactivity
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DOI: 10.1021/acs.organomet.7b00254
Abstract: The synthesis of ruthenium carbene complex PhSO2(Ph2PNSiMe3)C═Ru(p-cymene) (3) and its application in cooperative bond activation reactions were studied. Compound 3 is accessible via salt metathesis using the dilithium methandiide ligand or alternatively via dehydrohalogenation of… read more here.
Keywords: bond; ruthenium carbene; carbene complex; complex phso2 ... See more keywords
Ruthenium Carbene-Mediated Construction of Strained Allenes via the Enyne Cross-Metathesis/Cyclopropanation of 1,6-Enynes.
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DOI: 10.1021/acs.orglett.9b04662
Abstract: Herein, we report on the unprecedented dimerization of 1,6-enynes using a commercially available ruthenium complex RuCl2(PPh3)3, which results in a series of bicyclo[3.1.0]hexyl allene derivatives in moderate to excellent yields. Mechanistic investigation indicates that the… read more here.
Keywords: ruthenium; mediated construction; ruthenium carbene; carbene mediated ... See more keywords