Regioselective Annulation of Allenylphosphine Oxides with Aromatic Amides under Ruthenium(II) Catalysis.
Sign Up to like & getrecommendations! Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c01125
Abstract: Engaging allenes in transition-metal-catalyzed C-H bond activation strategy is immensely promising to access high-value scaffolds. However, such a reaction manifold remains largely elusive using cheap and sustainable ruthenium catalysis. We disclose an unprecedented ruthenium-catalyzed (4… read more here.
Keywords: aromatic amides; allenylphosphine oxides; ruthenium catalysis; regioselective annulation ... See more keywords
Remote C–H Functionalizations by Ruthenium Catalysis
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DOI: 10.1055/a-1485-5156
Abstract: Synthetic transformations of otherwise inert C–H bonds have emerged as a powerful tool for molecular modifications during the last decades, with broad applications towards pharmaceuticals, material sciences, and crop protection. Consistently, a key challenge in… read more here.
Keywords: remote functionalizations; chemistry; functionalizations ruthenium; catalysis ... See more keywords
Synthesis of Cytogenin Analogues by C(sp 2 )–H Functionalization under Ruthenium(II) Catalysis, and DFT Analysis
Sign Up to like & getrecommendations! Published in 2025 at "Synlett"
DOI: 10.1055/a-2564-5919
Abstract: The first concise and convenient synthesis of natural products, antibiotics, and anticancer agents resembling cytogenin and other isocoumarins has been achieved by using three components (an N -aroyl β-amino ester, an MBH acetate, and N… read more here.
Keywords: synthesis; synthesis cytogenin; ruthenium catalysis;