Diverse Functionalization of Ruthenium-Chelated 2-Picolylamines: Oxygenation, Dehydrogenation, Cyclization, and N-Dealkylation.
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DOI: 10.1021/acs.inorgchem.9b03065
Abstract: "Chemical noninnocence" of metal-coordinated 2-picolylamine (PA) derivatives has been introduced upon its reaction with the metal precursor [RuII(Cl)(H)(CO)(PPh3)3] under basic conditions. This in effect leads to the facile formation of metalated amide, imine, ring-cyclized pyrrole,… read more here.
Keywords: dealkylation; dehydrogenation; diverse functionalization; ruthenium chelated ... See more keywords