Articles with "ruthenium complex" as a keyword



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Potential anticancer applications of the novel naringin-based ruthenium (II) complex

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Published in 2019 at "3 Biotech"

DOI: 10.1007/s13205-019-1718-4

Abstract: Ruthenium seems to be a promising alternative to platinum because of the wide range of oxidation states it has and its ability to form complexes with bioactive ligands. In this study, naringin, a naturally occurring… read more here.

Keywords: ruthenium; complex potential; anticancer applications; ruthenium complex ... See more keywords
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Photovoltaic cells based on ternary P3HT:PCBM: Ruthenium(II) complex bearing 8-(diphenylphosphino)quinoline active layer

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Published in 2021 at "Colloids and Surfaces A: Physicochemical and Engineering Aspects"

DOI: 10.1016/j.colsurfa.2021.126685

Abstract: Abstract Optical, morphological and photovoltaic properties are investigated for ternary solar cells containing a traditional poly(3-hexylthiophene-2,5-diyl):[6,6]-phenyl-C61-butyric-acid-methyl ester (P3HT:PCBM) bulkheterojunction (BHJ) active layer modified with different concentrations of a novel ruthenium complex [Ru(N-P)2(O-O)], where N-P abbreviates… read more here.

Keywords: p3ht pcbm; active layer; layer; ruthenium complex ... See more keywords
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Three-dimensional high-rate electropolymerized thin film with exceptionally high photocurrent based on a triphenylamine-containing ruthenium complex

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Published in 2019 at "Electrochimica Acta"

DOI: 10.1016/j.electacta.2018.12.066

Abstract: Abstract A novel ruthenium complex capped with three triphenylamine units was synthesized and was high-rate anodically electropolymerized to form dense thin films of 33-nm thickness/per potential cycle on indium-tin oxide (ITO) electrodes. The films were… read more here.

Keywords: photocurrent; microscopy; ruthenium complex; film ... See more keywords
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Near-infrared light photocatalysis enabled by a ruthenium complex-integrated metal–organic framework via two-photon absorption

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Published in 2022 at "iScience"

DOI: 10.1016/j.isci.2022.104064

Abstract: Summary Photocatalysis under UV/visible light irradiation has emerged as one of the green methodologies for solar energy utilization and organic synthesis. These photocatalytic processes are typically initiated by one-photon-absorbing metal complexes or organic dyes. Nevertheless,… read more here.

Keywords: ruthenium complex; light irradiation; irradiation; metal organic ... See more keywords
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A stable ruthenium complex bearing a 1,2-dicarbadodecaborane(12)-1,2-dithiolate ligand and its activation for olefin metathesis

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Published in 2018 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2018.02.009

Abstract: Abstract In this article, a new ruthenium carbene catalyst containing a N-heterocyclic carbene, a pyridine-appended benzylidene carbene, and a 1,2-dicarbadodecab- orane(12)-1,2-dithiolate ligand was synthesized. The ruthenium complex is very stable in air or in solution… read more here.

Keywords: ruthenium; olefin metathesis; ruthenium complex; dithiolate ligand ... See more keywords
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Highly sensitive detection of Hg2+ using ruthenium complex-based probe in water

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Published in 2021 at "Journal of Organometallic Chemistry"

DOI: 10.1016/j.jorganchem.2021.121690

Abstract: Abstract A new ruthenium complex using 2-(2-thienyl)pyridine as cyclometalating ligand and 2,2’-bipyridine-5,5’-dicarboxylic acid as anchoring ligands was successfully synthesized and used as an Hg2+ colorimetric probe. Upon adding Hg2+ into the aqueous solution of the… read more here.

Keywords: hg2; water; ruthenium complex; probe ... See more keywords
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Multiphotochromism in an Asymmetric Ruthenium Complex with Two Different Dithienylethenes.

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Published in 2017 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.7b02023

Abstract: An asymmetric bis(dithienylethene-acetylide) ruthenium(II) complex trans-Ru(dppe)2(L1o)(L2o) (1oo) incorporating two different dithienylethene-acetylides (L1o and L2o) was designed to modulate multistate photochromism in view of the well separated ring-closing absorption bands between L1o and L2o. Upon irradiation… read more here.

Keywords: ruthenium complex; trans dppe; l1o l2o; two different ... See more keywords
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Characterization of a Ruthenium(II) Complex in Singlet Oxygen-Mediated Photoelectrochemical Sensing

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Published in 2022 at "Langmuir"

DOI: 10.1021/acs.langmuir.2c03042

Abstract: A water-soluble ruthenium(II) complex (L), capable of producing singlet oxygen (1O2) when irradiated with visible light, was used to modify the surface of an indium–tin oxide (ITO) electrode decorated with a nanostructured layer of TiO2… read more here.

Keywords: singlet; ruthenium complex; spectroscopy; singlet oxygen ... See more keywords
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Monomeric Octahedral Ruthenium(II) Complex Enabled meta-C-H Nitration of Arenes with Removable Auxiliaries.

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Published in 2017 at "Organic letters"

DOI: 10.1021/acs.orglett.7b01297

Abstract: A removable oxime-assisted meta-C-H nitration of arenes is reported. Mechanistic investigations and DFT calculations reveal a new monomeric octahedral ruthenium(II) complex is responsible for the meta-selective nitration. Dioxygen as a cooxidant is crucial for achieving… read more here.

Keywords: meta nitration; nitration; octahedral ruthenium; ruthenium complex ... See more keywords
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Octahedral Ruthenium Complex with Exclusive Metal-Centered Chirality for Highly Effective Asymmetric Catalysis.

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Published in 2017 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.7b01098

Abstract: A novel ruthenium catalyst is introduced which contains solely achiral ligands and acquires its chirality entirely from octahedral centrochirality. The configurationally stable catalyst is demonstrated to catalyze the alkynylation of trifluoromethyl ketones with very high… read more here.

Keywords: ruthenium; complex exclusive; chirality; exclusive metal ... See more keywords
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Ex Vivo Tracking of Endogenous CO with a Ruthenium(II) Complex.

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Published in 2017 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.7b11158

Abstract: A two-photon fluorescent probe based on a ruthenium(II) vinyl complex is capable of selectively detecting carbon monoxide in cells and ex vivo using mice with a subcutaneous air pouch as a model for inflammation. This… read more here.

Keywords: ruthenium; vivo; vivo tracking; endogenous ruthenium ... See more keywords