Structurally MMO Active Site‐like Ruthenium Complex for Catalytic Oxidation of Olefins to Aldehydes
Sign Up to like & getrecommendations! Published in 2025 at "Asian Journal of Organic Chemistry"
DOI: 10.1002/ajoc.202500201
Abstract: Unexpectedly synthesized a structurally MMO active site‐like new ruthenium complex and found that the complex showed high catalytic activity and selectivity for C=C double bond oxidative cleavage reaction in this paper. The ruthenium‐catalyzed oxidation reaction… read more here.
Keywords: ruthenium; site like; active site; mmo active ... See more keywords
Potential anticancer applications of the novel naringin-based ruthenium (II) complex
Sign Up to like & getrecommendations! Published in 2019 at "3 Biotech"
DOI: 10.1007/s13205-019-1718-4
Abstract: Ruthenium seems to be a promising alternative to platinum because of the wide range of oxidation states it has and its ability to form complexes with bioactive ligands. In this study, naringin, a naturally occurring… read more here.
Keywords: ruthenium; complex potential; anticancer applications; ruthenium complex ... See more keywords
Photovoltaic cells based on ternary P3HT:PCBM: Ruthenium(II) complex bearing 8-(diphenylphosphino)quinoline active layer
Sign Up to like & getrecommendations! Published in 2021 at "Colloids and Surfaces A: Physicochemical and Engineering Aspects"
DOI: 10.1016/j.colsurfa.2021.126685
Abstract: Abstract Optical, morphological and photovoltaic properties are investigated for ternary solar cells containing a traditional poly(3-hexylthiophene-2,5-diyl):[6,6]-phenyl-C61-butyric-acid-methyl ester (P3HT:PCBM) bulkheterojunction (BHJ) active layer modified with different concentrations of a novel ruthenium complex [Ru(N-P)2(O-O)], where N-P abbreviates… read more here.
Keywords: p3ht pcbm; active layer; layer; ruthenium complex ... See more keywords
Three-dimensional high-rate electropolymerized thin film with exceptionally high photocurrent based on a triphenylamine-containing ruthenium complex
Sign Up to like & getrecommendations! Published in 2019 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2018.12.066
Abstract: Abstract A novel ruthenium complex capped with three triphenylamine units was synthesized and was high-rate anodically electropolymerized to form dense thin films of 33-nm thickness/per potential cycle on indium-tin oxide (ITO) electrodes. The films were… read more here.
Keywords: photocurrent; microscopy; ruthenium complex; film ... See more keywords
Near-infrared light photocatalysis enabled by a ruthenium complex-integrated metal–organic framework via two-photon absorption
Sign Up to like & getrecommendations! Published in 2022 at "iScience"
DOI: 10.1016/j.isci.2022.104064
Abstract: Summary Photocatalysis under UV/visible light irradiation has emerged as one of the green methodologies for solar energy utilization and organic synthesis. These photocatalytic processes are typically initiated by one-photon-absorbing metal complexes or organic dyes. Nevertheless,… read more here.
Keywords: ruthenium complex; light irradiation; irradiation; metal organic ... See more keywords
A stable ruthenium complex bearing a 1,2-dicarbadodecaborane(12)-1,2-dithiolate ligand and its activation for olefin metathesis
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2018.02.009
Abstract: Abstract In this article, a new ruthenium carbene catalyst containing a N-heterocyclic carbene, a pyridine-appended benzylidene carbene, and a 1,2-dicarbadodecab- orane(12)-1,2-dithiolate ligand was synthesized. The ruthenium complex is very stable in air or in solution… read more here.
Keywords: ruthenium; olefin metathesis; ruthenium complex; dithiolate ligand ... See more keywords
Highly sensitive detection of Hg2+ using ruthenium complex-based probe in water
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2021.121690
Abstract: Abstract A new ruthenium complex using 2-(2-thienyl)pyridine as cyclometalating ligand and 2,2’-bipyridine-5,5’-dicarboxylic acid as anchoring ligands was successfully synthesized and used as an Hg2+ colorimetric probe. Upon adding Hg2+ into the aqueous solution of the… read more here.
Keywords: hg2; water; ruthenium complex; probe ... See more keywords
Multiphotochromism in an Asymmetric Ruthenium Complex with Two Different Dithienylethenes.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b02023
Abstract: An asymmetric bis(dithienylethene-acetylide) ruthenium(II) complex trans-Ru(dppe)2(L1o)(L2o) (1oo) incorporating two different dithienylethene-acetylides (L1o and L2o) was designed to modulate multistate photochromism in view of the well separated ring-closing absorption bands between L1o and L2o. Upon irradiation… read more here.
Keywords: ruthenium complex; trans dppe; l1o l2o; two different ... See more keywords
Characterization of a Ruthenium(II) Complex in Singlet Oxygen-Mediated Photoelectrochemical Sensing
Sign Up to like & getrecommendations! Published in 2022 at "Langmuir"
DOI: 10.1021/acs.langmuir.2c03042
Abstract: A water-soluble ruthenium(II) complex (L), capable of producing singlet oxygen (1O2) when irradiated with visible light, was used to modify the surface of an indium–tin oxide (ITO) electrode decorated with a nanostructured layer of TiO2… read more here.
Keywords: singlet; ruthenium complex; spectroscopy; singlet oxygen ... See more keywords
Monomeric Octahedral Ruthenium(II) Complex Enabled meta-C-H Nitration of Arenes with Removable Auxiliaries.
Sign Up to like & getrecommendations! Published in 2017 at "Organic letters"
DOI: 10.1021/acs.orglett.7b01297
Abstract: A removable oxime-assisted meta-C-H nitration of arenes is reported. Mechanistic investigations and DFT calculations reveal a new monomeric octahedral ruthenium(II) complex is responsible for the meta-selective nitration. Dioxygen as a cooxidant is crucial for achieving… read more here.
Keywords: meta nitration; nitration; octahedral ruthenium; ruthenium complex ... See more keywords
Sonoinduced Tumor Therapy and Metastasis Inhibition by a Ruthenium Complex with Dual Action: Superoxide Anion Sensitization and Ligand Fracture.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c08278
Abstract: Photoresponsive ruthenium(II) complexes have recently emerged as a promising tool for synergistic photodynamic therapy and chemotherapy in oncology, as well as for antimicrobial applications. However, the limited penetration power of photons prevents the treatment of… read more here.
Keywords: ruthenium; ligand fracture; ruthenium complex; therapy ... See more keywords