Oxidation of Hypophosphorous Acid by a Ruthenium(VI) Nitrido Complex in Aqueous Acidic Solution. Evidence for a Proton-Coupled N-Atom Transfer Mechanism.
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DOI: 10.1021/acs.inorgchem.2c01627
Abstract: The oxidation of hypophosphorous acid (H3PO2) by a ruthenium(VI) nitrido complex, [(L)RuVI(N)(OH2)]+ (RuVIN; L = N,N'-bis(salicylidene)-o-cyclohexyldiamine dianion), has been studied in aqueous acidic solutions at pH 0-2.50. The reaction has the following stoichiometry: 2[(L)RuVI(N)(OH2)]+ +… read more here.
Keywords: nitrido complex; oxidation; oxidation hypophosphorous; ruthenium nitrido ... See more keywords
Facile C-N bond cleavage of primary aliphatic amines by (salen)ruthenium(VI) nitrido complexes.
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DOI: 10.1039/d2dt00600f
Abstract: We report the first example of oxidative cleavage of the strong C-N bonds of primary amines by a ruthenium(VI) nitrido complex. The driving force for this very fast C-N cleavage reaction comes from the formation… read more here.
Keywords: cleavage; bond cleavage; ruthenium nitrido; facile bond ... See more keywords