Articles with "ruthenium nitrosyl" as a keyword



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Nitric oxide photo-release from a ruthenium nitrosyl complex with a 4,4′-bisfluorenyl-2,2′-bipyridine ligand

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Published in 2018 at "Polyhedron"

DOI: 10.1016/j.poly.2018.05.028

Abstract: Abstract A ruthenium nitrosyl complex of formula [RuII(terpy)(F2B)(NO)](PF6)3, where terpy stands for 2,2′:6′,2″-terpyridine and F2B for 4,4′-bis(9,9′-dibutyl-9H-fluoren-2-yl)-2,2′-bipyridine, is presented and fully characterized. The X-ray crystal structure of F2B is reported. The electronic properties of the… read more here.

Keywords: terpy; nitrosyl complex; ruthenium nitrosyl; f2b ... See more keywords
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Ruthenium Nitrosyl Structure in Solvent Extraction Systems: A Comparison of Tributyl Phosphate, Tetrabutyl Urea, N-Methyl, N-Octyl Ethylhexanamide, and N,N,N′,N′-Tetraoctyl Diglycolamide

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Published in 2019 at "Industrial & Engineering Chemistry Research"

DOI: 10.1021/acs.iecr.9b02555

Abstract: In the course of nuclear fuel treatment, solvent extraction cycles separate uranium and plutonium from fission products and minor actinides. During these steps, small amounts of the fission product... read more here.

Keywords: solvent extraction; structure solvent; nitrosyl structure; extraction systems ... See more keywords
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Photorelease of nitric oxide (NO) on ruthenium nitrosyl complexes with phenyl substituted terpyridines

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Published in 2017 at "New Journal of Chemistry"

DOI: 10.1039/c7nj00866j

Abstract: We investigated the influence of the nature of the substituent on the 4′-position of terpyridine ligands and the geometry around the metal ion on the photosensitization of ruthenium nitrosyl complexes. This was achieved by synthesizing… read more here.

Keywords: phtpy cl2; nitrosyl complexes; ruthenium nitrosyl;
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Ruthenium-nitrosyl complexes as NO-releasing molecules, potential anticancer drugs, and photoswitches based on linkage isomerism.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt00290f

Abstract: The synthesis of new types of mono- and polynuclear ruthenium nitrosyl complexes is driving progress in the field of NO generation for a variety of applications. Light-induced Ru-NO bond dissociation in solution may involve transient… read more here.

Keywords: potential anticancer; nitrosyl complexes; ruthenium nitrosyl; anticancer drugs ... See more keywords
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A ruthenium nitrosyl complex-based highly selective colorimetric sensor for biological H2S and H2S-NO cross-talk regulated release of NO.

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Published in 2022 at "Dalton transactions"

DOI: 10.1039/d2dt03108f

Abstract: A ruthenium nitrosyl complex (1·NO) and 1·NO incorporated phospholipid-based liposomes (Lip-1·NO) were reported for highly selective colorimetric detection of H2S. The probe 1·NO "cross-talks" with H2S and releases nitric oxide (NO) in the process. The… read more here.

Keywords: nitrosyl complex; spectroscopy; ruthenium nitrosyl; cross ... See more keywords
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Bismuth and antimony halometalates containing photoswitchable ruthenium nitrosyl complexes.

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Published in 2023 at "Dalton transactions"

DOI: 10.1039/d2dt03497b

Abstract: The first examples of Bi(III) and Sb(III) halide compounds combined with a photoswitchable ruthenium nitrosyl unit are reported. The structures of [RuNOPy4Br]4[Sb2Br8][Sb3Br12]2 (1) and (H3O)[RuNOPy4Br]4[Bi2Br9]3·3H2O (2) were determined by X-ray diffraction, and exhibit three different… read more here.

Keywords: bismuth antimony; photoswitchable ruthenium; ruthenium nitrosyl; antimony halometalates ... See more keywords