Cyclic (Alkyl)(amino)carbenes (CAACs) in Ruthenium Olefin Metathesis
Sign Up to like & getrecommendations! Published in 2021 at "ACS Catalysis"
DOI: 10.1021/acscatal.0c05508
Abstract: Discovered in 2005, cyclic (alkyl)(amino)carbenes (CAACs) have led to numerous discoveries in the field of ruthenium olefin metathesis, until then largely dominated by the well-known N-heterocyclic... read more here.
Keywords: amino carbenes; carbenes caacs; olefin metathesis; ruthenium olefin ... See more keywords
Stable ruthenium olefin metathesis catalysts bearing symmetrical NHC ligands with primary and secondary N-alkyl groups.
Sign Up to like & getrecommendations! Published in 2018 at "Dalton transactions"
DOI: 10.1039/c8dt00619a
Abstract: Four novel stable Hoveyda-Grubbs-type catalysts containing N,N'-dineopentyl- and N,N'-dicyclohexyl-substituted N-heterocyclic carbene (NHC) ligands with syn and anti phenyl groups on the ring backbone were synthesized and fully characterized. The catalytic potential of these complexes was… read more here.
Keywords: ruthenium olefin; catalysts bearing; stable ruthenium; metathesis ... See more keywords