A covalently linked nickel(II) porphyrin-ruthenium(II) tris(bipyridyl) dyad for efficient photocatalytic water oxidation.
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DOI: 10.1039/d2cc03563d
Abstract: Visible-light-induced oxidation of water to dioxygen, catalyzed by a newly synthesized NiP-Ru dyad consisting of a ruthenium tris(bipyridyl), [Ru(bpy)3]2+ as a photosensitizer, and a low-cost nickel porphyrin, NiP as a water oxidation catalyst is reported. read more here.
Keywords: nickel porphyrin; oxidation; tris bipyridyl; water oxidation ... See more keywords
Ruthenium tris(σ-B-H) borate complexes: synthesis, structure, and reactivity.
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DOI: 10.1039/d2dt03092f
Abstract: The coordination of the B-H bond to a transition metal is fundamentally intriguing due to its connection with the transition metal-mediated B-H bond activation mechanism and catalysis. Most of the reported examples are σ-borane/borate complexes… read more here.
Keywords: borate; ruthenium tris; transition metal; borate complexes ... See more keywords