A Cubic Heptanuclear Cobalt(II) Bis(Salamo)‐Type Cluster: Structural, Spectroscopic, and Computational Studies
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DOI: 10.1002/aoc.70014
Abstract: A cube‐like heptanuclear cobalt(II) cluster single crystals, namely, [Co7(L)2(μ3‐OCH3)2(μ3‐OH)4](ClO4)2, was successfully grown up by reacting of a bis(salamo)‐type ligand H3L containing two N2O2 coordination cavities with Co(NO3)2·6H2O using natural volatilization method. Single‐crystal analysis displayed that… read more here.
Keywords: cobalt; salamo type; cluster; bis salamo ... See more keywords
Exploration of the Differences in Coordination Behaviors and Spectrographic Properties of Two Novel Seven‐Nucleated Ni (II) Complexes of a Salamo‐Type Flexible‐Bisoxime Ligand
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DOI: 10.1002/aoc.7890
Abstract: A salamo‐type bis‐oxime ligand H2L was synthesized, which reacted with Ni (NO3)2·6H2O in different reaction solvents to synthesize two novel heptanuclear Ni (II) complexes: [Ni7(L)3(μ3‐OH)8(EtOH)6]·2CH2Cl2 (1) and [Ni7(L)3(μ3‐OMe)2(μ3‐OH)6(MeOH)6]·CH2Cl2 (2). X‐ray crystal diffraction results showed that… read more here.
Keywords: differences coordination; salamo type; exploration differences; ligand ... See more keywords