Articles with "salen" as a keyword



Iron–Salen Complex and Co2+ Ion‐Derived Cobalt–Iron Hydroxide/Carbon Nanohybrid as an Efficient Oxygen Evolution Electrocatalyst

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Published in 2019 at "Advanced Science"

DOI: 10.1002/advs.201900117

Abstract: Abstract Metal–salen complexes are widely used as catalysts in numerous fundamental organic transformation reactions. Here, CoFe hydroxide/carbon nanohybrid is reported as an efficient oxygen evolution electrocatalyst derived from the in situ formed molecular Fe–salen complexes… read more here.

Keywords: salen; efficient oxygen; carbon nanohybrid; hydroxide carbon ... See more keywords

Design, Synthesis, Physicochemical Characterization, and Prospective Pharmaceutical Applications of Novel Tetra‐Dentate Salen Complexes: DFT and Molecular Docking Insights

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Published in 2025 at "Applied Organometallic Chemistry"

DOI: 10.1002/aoc.70269

Abstract: Some novel salen metal chelates of Cu(II), Ni(II), VO(II), and Pd(II) were synthesized using the ligand 2,2'‐((1E,1'E)‐((4, 5‐dimethyl‐1,2‐phenylene) bis(azaneylylidene)) bis(methaneylylidene)) bis(4‐bromophenol). These complexes were extensively characterized through m.p., elemental analysis, TGA, conductivity, and UV–visible spectroscopy.… read more here.

Keywords: molecular docking; docking insights; complexes dft; salen ... See more keywords

Copolymerization of transition metal salen complexes and conversion into metal nanoparticles supported on hierarchically porous carbon monoliths: a one pot synthesis

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Published in 2017 at "Journal of Sol-Gel Science and Technology"

DOI: 10.1007/s10971-017-4510-0

Abstract: Described is the synthesis of metal (Ni, Cr, and Mn) doped macro/mesoporous carbon monoliths by co-polymerization of transition metal complexes with resorcinol/formaldehyde and subsequent pyrolysis. Two salen ligands were synthesized via reaction of ethylene diamine… read more here.

Keywords: salen complexes; salen; transition metal; metal salen ... See more keywords

Enantioselective Photocatalysis Using a Privileged Al-Salen Complex.

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Published in 2025 at "Accounts of chemical research"

DOI: 10.1021/acs.accounts.5c00194

Abstract: ConspectusEnantioselective catalysts that exhibit broad generality are disruptive innovators in contemporary synthesis and are considered to be "privileged" on account of their expansive reactivity/selectivity profiles. Operating in the ground state, these species simultaneously regulate reactivity… read more here.

Keywords: ground state; salen complex; salen; activation ... See more keywords

Highly Efficient Visible-Light-Driven CO2-to-CO Conversion by Coordinatively Unsaturated Co-Salen Complexes in a Water-Containing System.

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Published in 2022 at "Inorganic chemistry"

DOI: 10.1021/acs.inorgchem.2c02515

Abstract: The development of cost-effective catalysts for CO2 reduction is highly desired but remains a significant challenge. The unsaturated coordination metal center in a catalyst is favorable for the process of catalytic CO2 reduction. In this… read more here.

Keywords: coordinatively unsaturated; unsaturated salen; salen; visible light ... See more keywords

Synthetic and Mechanistic Studies into the Reductive Functionalization of Nitro Compounds Catalyzed by an Iron(salen) Complex

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Published in 2024 at "Journal of the American Chemical Society"

DOI: 10.1021/jacs.4c02797

Abstract: We report on the use of a simple, bench-stable [Fe(salen)2]-μ-oxo precatalyst in the reduction of nitro compounds. The reaction proceeds at room temperature across a range of substrates, including nitro aromatics and aliphatics. By changing… read more here.

Keywords: chemistry; nitro compounds; iron; synthetic mechanistic ... See more keywords

Palladium–salen-bridged ionic networks immobilized on magnetic dendritic silica fibers for the synthesis of cyclic carbonates by oxidative carboxylation

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Published in 2020 at "New Journal of Chemistry"

DOI: 10.1039/c9nj05513d

Abstract: Compared to epoxides, converting carbon dioxide (CO2) to cyclic carbonates is proposed as the most appropriate way to synthesize C1 building blocks. In this study, a Pd(II) Schiff base complex is fixed on FeNi3/DFNS nanoparticles… read more here.

Keywords: feni3 dfns; salen; dfns nanoparticles; carboxylation ... See more keywords