A Mn(salen)‐Based Artificial Metalloenzyme for Nitrene and Oxene Transfer Catalysis
Sign Up to like & getrecommendations! Published in 2024 at "ChemBioChem"
DOI: 10.1002/cbic.202400774
Abstract: The development of artificial metalloenzymes (ArMs) offers a potent approach to incorporate non‐natural chemical reactions into biocatalysis. Here we report the assembly of Mn(salen)‐based ArMs by embedding biotinylated Mn(salen) complexes into streptavidin (Sav) variants. Using… read more here.
Keywords: artificial metalloenzyme; metalloenzyme nitrene; transfer; nitrene oxene ... See more keywords
A chiral salen-based MOF catalytic material with high thermal, aqueous and chemical stabilities.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01116d
Abstract: A highly stable chiral salen-based metal-organic framework [(Cu4I4)2L4]·20DMF·3CH3CN (1) [L = (R,R)-N,N'-bis(3-tert-butyl-5-(4-pyridyl)salicylidene)-1,2-diphenylethylenediamine nickel(ii)] has been synthesized and characterized by single crystal X-ray diffraction and other physicochemical methods. 1 exhibits a rare 8-fold interpenetrated 3D framework… read more here.
Keywords: mof catalytic; salen based; solution; catalytic material ... See more keywords
A salen-based dinuclear cobalt(ii) polymer with direct and indirect synergy for electrocatalytic hydrogen evolution
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DOI: 10.1039/d5sc02073e
Abstract: Optimizing the spatial arrangement and geometric configuration of dinuclear metal sites within catalysts to leverage the dinuclear metal synergistic catalysis (DMSC) effect is a promising strategy for enhancing catalytic performance. In this work, we report… read more here.
Keywords: hydrogen evolution; based dinuclear; salen based; dinuclear cobalt ... See more keywords
Preparation of Salen-based polyphosphoronitrile microspheres composite LDH and study of epoxy composite properties
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DOI: 10.1177/09540083251364502
Abstract: This paper describes the preparation of organic-inorganic hybrid flame retardants obtained by compositing Salen-based polyphosphonitrile microspheres with layered double hydroxide (LDH) phases. The flame retardants were applied to the effects of varying the mass ratio… read more here.
Keywords: ldh; flame retardants; preparation salen; salen based ... See more keywords
Two Novel Salen Based Chemosensors for Selective Recognition of Zinc(II) Ion
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DOI: 10.20964/2018.09.71
Abstract: Two novel salen based chemosensors were synthesized and identified by FT-IR, 1 H-NMR and Elemental analysis. We evaluated the selectivity and sensitivity of probe L1 and L2 toward zinc ions via UV-vis, Cyclic voltammetry and… read more here.
Keywords: novel salen; zinc; based chemosensors; salen based ... See more keywords