Chiral salen Mn (III) immobilized on ZnPS-PVPA through alkoxyl-triazole for superior performance catalyst in asymmetric epoxidation of unfunctionalized olefins
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.02.008
Abstract: Abstract Chiral salen Mn (III) catalysts anchored onto ZnPS-PVPA via click chemistry are prepared and applied in asymmetric epoxidations of unfunctionalized olefins. Superior catalytic performances (conv%, up to >99; ee%, up to >99) are achieved… read more here.
Keywords: unfunctionalized olefins; salen iii; chiral salen; iii immobilized ... See more keywords
Investigation on catecholase activity of salen Co(III) octahedral complexes
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114129
Abstract: Abstract We have synthesized three octahedral Co(III) compounds in order to study their catalytic efficiency for the oxidation of 3,5-di-tertiarybutylcatechol (3,5-DTBC) into the corresponding quinone. Among the tested compounds, only one compound, 3 shows the… read more here.
Keywords: catecholase activity; investigation catecholase; activity salen; catecholase ... See more keywords
Salen(Co(iii)) imprisoned within pores of a metal-organic framework by post-synthetic modification and its asymmetric catalysis for CO2 fixation at room temperature.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc06522a
Abstract: Herein, a new preparation strategy of chiral metal-organic frameworks (CMOFs) has been demonstrated. By adsorption and then post-synthetically modified (PSM) procedures, chiral salen(Co(iii)) could be imprisoned within the cages of an MOF and remained in… read more here.
Keywords: metal organic; room temperature; post; imprisoned within ... See more keywords
(Salen)Mn(iii)-catalyzed chemoselective acylazidation of olefins††Electronic supplementary information (ESI) available. CCDC 1546115. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c8sc01882k
Sign Up to like & getrecommendations! Published in 2018 at "Chemical Science"
DOI: 10.1039/c8sc01882k
Abstract: A (salen)Mn(iii)-catalyzed chemoselective acylazidation of olefins was developed based on strategic application of the distinct reactivity of oxomanganese(v) species. read more here.
Keywords: acylazidation olefins; catalyzed chemoselective; iii catalyzed; chemoselective acylazidation ... See more keywords