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Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.02.008
Abstract: Abstract Chiral salen Mn (III) catalysts anchored onto ZnPS-PVPA via click chemistry are prepared and applied in asymmetric epoxidations of unfunctionalized olefins. Superior catalytic performances (conv%, up to >99; ee%, up to >99) are achieved…
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Keywords:
unfunctionalized olefins;
salen iii;
chiral salen;
iii immobilized ... See more keywords
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Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114129
Abstract: Abstract We have synthesized three octahedral Co(III) compounds in order to study their catalytic efficiency for the oxidation of 3,5-di-tertiarybutylcatechol (3,5-DTBC) into the corresponding quinone. Among the tested compounds, only one compound, 3 shows the…
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Keywords:
catecholase activity;
investigation catecholase;
activity salen;
catecholase ... See more keywords
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Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc06522a
Abstract: Herein, a new preparation strategy of chiral metal-organic frameworks (CMOFs) has been demonstrated. By adsorption and then post-synthetically modified (PSM) procedures, chiral salen(Co(iii)) could be imprisoned within the cages of an MOF and remained in…
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Keywords:
metal organic;
room temperature;
post;
imprisoned within ... See more keywords
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Published in 2018 at "Chemical Science"
DOI: 10.1039/c8sc01882k
Abstract: A (salen)Mn(iii)-catalyzed chemoselective acylazidation of olefins was developed based on strategic application of the distinct reactivity of oxomanganese(v) species.
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Keywords:
acylazidation olefins;
catalyzed chemoselective;
iii catalyzed;
chemoselective acylazidation ... See more keywords