Enhanced electrochemical performance of salen-type transition metal polymer with electron-donating substituents
Sign Up to like & getrecommendations! Published in 2019 at "Ionics"
DOI: 10.1007/s11581-018-2819-5
Abstract: Salen-type Schiff base transition metal monomers with substituents Ni (CH3-salen), Ni (CH3O-salen), and Ni (Cl-salen) have been synthesized and electro-polymerized onto the indium tin oxide substrate electrodes. The effect of electron-donating groups on the electrochemical… read more here.
Keywords: ch3o salen; polymer; poly; electron donating ... See more keywords
Metal-centered redox activity in a polymeric Cobalt(II) complex of a sterically hindered salen type ligand
Sign Up to like & getrecommendations! Published in 2020 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2020.136496
Abstract: Abstract This paper reports on the peculiarities of the metal-centered redox activity in a polymeric cobalt(II) complex of a sterically hindered tetradentate N2O2 Schiff base (salen type) ligand. A Co(III)/Co(II) redox process in the polymer… read more here.
Keywords: redox activity; redox; sterically hindered; metal centered ... See more keywords
Dipolar state assisted aggregation induced optical behavior of push-pull Salen-type Schiff base (BIHyDE) in solution
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Molecular Structure"
DOI: 10.1016/j.molstruc.2021.130140
Abstract: Abstract Aggregation behavior of push-pull salen-type schiff base (BIHyDE) in different solvents at ground and excited state, has been investigated. At ground state, lower energy absorption band is suppressed during concentration dependent UV-Vis study in… read more here.
Keywords: salen type; aggregation; push pull; state ... See more keywords
Structural effect on NIR luminescence of three salen type heteropolynuclear 3d − 4f erbium complexes
Sign Up to like & getrecommendations! Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114811
Abstract: Abstract Three rigid hexadentate salen-type (H2L) Zn − Er complexes, namely [ErZnL(OAc)3] (1), [ErZn2L2(OAc)2)](PF6)·CH3OH·CH3Cl2 (2) and [Er4Zn2L2(OAc)10(CH3OH)4](PF6)2·2CH3OH·2H2O (3) (H2L = N,N'-bis(2-oxy-3-methoxybenzylidene)-1,2-phenylenediamine), have been isolated by the reactions of H2L with Er(OAc)3·6H2O salts. The introduction of the Zn2+ ion resulted… read more here.
Keywords: luminescence three; nir luminescence; structural effect; effect nir ... See more keywords
Water-stable [Ni(salen)]-type electrode material based on phenylazosubstituted salicylic aldehyde imine ligand
Sign Up to like & getrecommendations! Published in 2017 at "New Journal of Chemistry"
DOI: 10.1039/c7nj03526h
Abstract: A novel electrode material was prepared by electrochemical oxidation of [4,4′-phenylazo-2,2′-(ethylenediimino-κ2N-methyl)diphenolate-κ2O]nickel, a [Ni(II)(salen)]-type complex, in chlorinated solvent. The chemical structure of the material was explored by FTIR, NMR and XPS techniques to determine the main… read more here.
Keywords: water stable; electrode material; material; stable salen ... See more keywords
Dual responsive salen-type Schiff bases for the effective detection of L-arginine via a static quenching mechanism
Sign Up to like & getrecommendations! Published in 2018 at "New Journal of Chemistry"
DOI: 10.1039/c8nj02657b
Abstract: L-Arginine is one of the most important amino acids and plays a key role in diagnostic studies. Herein, we report four salen-type Schiff base fluorimetric/colorimetric sensors for the rapid detection of L-arginine. Substituents play a… read more here.
Keywords: detection arginine; type schiff; salen type;
Deaggregation properties and transmetalation studies of a zinc(II) salen-type Schiff-base complex.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt01448c
Abstract: This paper reports the synthesis and the deaggregation properties of a Lewis acidic Zn(II) salen-type Schiff-base complex derivative from diaminomaleonitrile and a systematic detailed study of its transmetalation with other metal ions in solution. In… read more here.
Keywords: transmetalation; base complex; salen type; deaggregation properties ... See more keywords
Asymmetric Monomer Design Enables Structural Control of M(Salen)-Type Polymers
Sign Up to like & getrecommendations! Published in 2023 at "Polymers"
DOI: 10.3390/polym15051127
Abstract: Conductive and electrochemically active polymers consisting of Salen-type metal complexes as building blocks are of interest for energy storage and conversion applications. Asymmetric monomer design is a powerful tool for fine-tuning the practical properties of… read more here.
Keywords: asymmetric monomer; monomer design; control; salen type ... See more keywords