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Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c14845
Abstract: Samarium diiodide (SmI2) exhibits high selectivity for N2R catalyzed by molybdenum complexes; however, it has so far been employed only as a stoichiometric reagent (0.3 equiv of NH3 per Sm) combined with coordinating proton sources…
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Keywords:
samarium;
catalytic electron;
samarium catalytic;
electron transfer ... See more keywords