Renaissance of Sandmeyer-Type Reactions: Conversion of Aromatic C-N Bonds into C-X Bonds (X = B, Sn, P, or CF3).
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DOI: 10.1021/acs.accounts.7b00566
Abstract: The Sandmeyer reaction represents an important organic transformation that converts an arylamine to an aryl halide using Cu(I) halide via a diazonium salt intermediate. The reaction was first reported by Sandmeyer in 1884, and a… read more here.
Keywords: chemistry; sandmeyer type; reaction; diazonium ... See more keywords
Reductive sandmeyer-type reaction for the synthesis of sulfoxides from anilines under photocatalysis
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DOI: 10.1039/d3qo00297g
Abstract: A reductive Sandmeyer-type sulfinylation reaction of aryldiazonium salts with sodium sulfinates is reported. The reaction takes place under photocatalysis, generating a range of valuable sulfoxides in a radical substitution pathway.... read more here.
Keywords: reaction; sandmeyer type; reductive sandmeyer; photocatalysis ... See more keywords