Bioactive half-sandwich Rh and Ir bipyridyl complexes containing artemisinin.
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DOI: 10.1016/j.jinorgbio.2021.111408
Abstract: Reaction of dihydroartemisinin (DHA) with 4-methyl-4'-carboxy-2,2'-bipyridine yielded the new ester derivative L1. Six novel organometallic half-sandwich chlorido Rh(III) and Ir(III) complexes (1-6) containing pentamethylcyclopentadienyl, (Cp*), tetramethylphenylcyclopentadienyl (Cpxph), or tetramethylbiphenylcyclopentadienyl (Cpxbiph), and N,N-chelated bipyridyl group of… read more here.
Keywords: sandwich bipyridyl; bioactive half; artemisinin; complexes containing ... See more keywords