Insights into the all-metal [Sb 3 Au 3 Sb 3 ] 3− sandwich complex from a QTAIM and stress tensor analysis
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DOI: 10.1016/j.cplett.2017.07.050
Abstract: Abstract A QTAIM investigation of the [Sb 3 Au 3 Sb 3 ] 3− sandwich complex is consistent with a previous investigation and reveals all of the bond critical points ( BCP s) to be… read more here.
Keywords: bcp; stress tensor; sandwich complex; tensor analysis ... See more keywords
Actinide arene-metalates: 2. A neutral uranium bis(anthracenide) sandwich complex and elucidation of its electronic structure.
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DOI: 10.1039/d2cc03238d
Abstract: An unprecedented sandwich complex of the actinides is synthesized from the treatment of [UI2(HMPA)4]I (HMPA = OP(NMe2)3) (2) with 3 equiv. of K(C14H10) to give the neutral, bis(arenide) species U(η6-C14H10)(η4-C14H10)(HMPA)2 (1). Solid-state X-ray, SQUID magnetometry,… read more here.
Keywords: sandwich; bis; electronic structure; sandwich complex ... See more keywords
A homoleptic tris(diphosphacyclobutadiene) tripledecker sandwich complex.
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DOI: 10.1039/d2cc04601f
Abstract: The synthesis and characterisation of [Co2(η4-P2C2tBu2)2(μ:η4:η4-P2C2tBu2)] (1) is described, featuring two cobalt atoms and three diphosphacyclobutadiene ligands. This compound is the first triple-decker sandwich complex which exclusively contains cyclobutadiene ligands. read more here.
Keywords: diphosphacyclobutadiene tripledecker; tris diphosphacyclobutadiene; sandwich complex; diphosphacyclobutadiene ... See more keywords