M(C6H6R)2 (R = BH, Be; M = Cr, Mo, W): Transition-metal sandwich complexes with η7-coordination borepin and beryllepin: A DFT study
Sign Up to like & getrecommendations! Published in 2019 at "Computational and Theoretical Chemistry"
DOI: 10.1016/j.comptc.2019.112562
Abstract: Abstract In this article, the geometrical and electronic structures of a series of borepin and beryllepin transition-metal sandwich complexes M(C6H6R)2 (R = BH, Be; M = Cr, Mo, W) have been systematically investigated at the B3LYP and BP86 levels… read more here.
Keywords: metal sandwich; sandwich complexes; transition metal; borepin beryllepin ... See more keywords
Naphthalene Diimide-Functionalized Half-Sandwich Ru(II) Complexes as Mitochondria-Targeted Anticancer and Antimetastatic Agents.
Sign Up to like & getrecommendations! Published in 2023 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.3c01125
Abstract: In this work, four naphthalene diimide (NDI)-functionalized half-sandwich Ru(II) complexes Ru1-Ru4 bearing the general formula [(η6-arene)RuII(N^N)Cl]PF6, where arene = benzene (bn), p-cymene (p-cym), 1,3,5-trimethylbenzene (tmb), and hexamethylbenzene (hmb), have been synthesized and characterized. By introducing… read more here.
Keywords: functionalized half; naphthalene diimide; half sandwich; sandwich complexes ... See more keywords
Zirconium arene triple-decker sandwich complexes: synthesis, electronic structure and bonding.
Sign Up to like & getrecommendations! Published in 2017 at "Chemical communications"
DOI: 10.1039/c7cc07083g
Abstract: Reduction of a permethylpentalene zirconium(iv) chloride complex [η8-Pn*Zr(μ-Cl)3/2]2(μ-Cl)2Li·THFx with KC8 in benzene results in activation of the aromatic solvent to yield an "inverted sandwich" complex, [η8-Pn*Zr]2(μ-η6:η6-C6H6) (1). The reactions in toluene, cumene, o-xylene and m-xylene… read more here.
Keywords: decker sandwich; triple decker; sandwich complexes; zirconium ... See more keywords
Di- and trinuclear sandwich complexes of a cross-conjugated fulvene.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03521a
Abstract: We report di- and trinuclear palladium sandwich complexes of cross-π-conjugated fulvenes. Structural and theoretical analysis revealed that a fulvene sandwich framework holds a metal-metal bonded moiety, where the dinuclear and trinuclear bonds feature strong donation… read more here.
Keywords: sandwich; trinuclear sandwich; sandwich complexes; cross conjugated ... See more keywords
From sandwich complexes to dendrimers: journey toward applications to sensing, molecular electronics, materials science, and biomedicine.
Sign Up to like & getrecommendations! Published in 2023 at "Chemical communications"
DOI: 10.1039/d3cc01175e
Abstract: This review links various areas of inorganic chemistry around the themes developed by our research group during the last four decades. It is firstly based on the electronic structure of iron sandwich complexes, showing how… read more here.
Keywords: redox sensing; sandwich complexes; redox; bond formation ... See more keywords
Cytotoxicity of osmium(II) and cycloosmated half-sandwich complexes from 1-pyrenyl-containing phosphane ligands.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d3dt00743j
Abstract: Five metal-arene complexes of formula [MX2(η6-p-cymene)(diR(1-pyrenyl)phosphane)] (M = Os or Ru, X = Cl or I, R = isopropyl or phenyl) and symbolized as MRX2 were synthesized and fully characterized, namely OsiPrCl2, OsiPrI2, OsPhCl2, OsPhI2… read more here.
Keywords: dir pyrenyl; phosphane; half sandwich; sandwich complexes ... See more keywords
Phosphanyl-substituted tin half-sandwich complexes
Sign Up to like & getrecommendations! Published in 2023 at "RSC Advances"
DOI: 10.1039/d3ra01384g
Abstract: Phosphanyl-substituted tin(ii) half sandwich complexes are reported. Due to the Lewis acidic tin center and Lewis basic phosphorous atom they form head-to-tail dimers. Their properties and reactivities were investigated both experimentally and theoretically. Furthermore, related… read more here.
Keywords: sandwich complexes; half sandwich; substituted tin; phosphanyl substituted ... See more keywords