Electronic Structure and Spin Transport Properties of a New Class of Semiconductor Surface-Confined One-Dimensional Half-Metallic [Eu-(CnHn–2)]N (n = 7–9) Sandwich Compounds and Molecular Wires: First Principle Studies
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DOI: 10.1021/acs.jpcc.8b04443
Abstract: Transition-metal atom/π-conjugated ring sandwich compounds are promising candidates for application in molecular spintronics. However, a great challenge that has significantly restrained the practical application of these sandwich compounds is their fabrication on a well-characterized solid-state… read more here.
Keywords: sandwich compounds; electronic structure; surface; cnhn ... See more keywords
Borylation, silylation and selenation of C–H bonds in metal sandwich compounds by applying a directing group strategy
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DOI: 10.1039/c7nj02388j
Abstract: Palladium-mediated borylation, silylation, and selenation have been achieved by C–H activation using bidentate directing groups linked on iron and cobalt sandwich compounds. Herein, the first examples of borylation and silylation using pyridine-N-oxide and (2-methylthio)phenyl directing… read more here.
Keywords: borylation silylation; silylation selenation; borylation; sandwich compounds ... See more keywords