Cyanosilylation of carbonyl compounds catalyzed by half-sandwich (η6-p-cymene) Ruthenium(II) complexes bearing heterocyclic hydrazone derivatives
Sign Up to like & getrecommendations! Published in 2021 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2020.120006
Abstract: Abstract A new class of half-sandwich (ƞ6-p-cymene) ruthenium(II) complexes supported by heterocyclic hydrazone derivatives of general formula [Ru(ƞ6-p-cymene)(Cl)(L)] where L represents N’-((1H-pyrrol-2-yl)methylene)furan-2-carbohydrazide (L1), N’-((1H-pyrrol-2-yl)methylene)thiophene-2-carbohydrazide (L2) or N’-((1H-pyrrol-2-yl)methylene)isonicotinohydrazide (L3) were synthesized. Both ligand precursors and complexes… read more here.
Keywords: heterocyclic hydrazone; cymene ruthenium; sandwich cymene; cymene ... See more keywords
Half-Sandwich Ru(p-cymene) Compounds with Diphosphanes: In Vitro and In Vivo Evaluation As Potential Anticancer Metallodrugs.
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DOI: 10.1021/acs.inorgchem.0c02768
Abstract: Ruthenium(II) complexes are currently considered attractive alternatives to the widely used platinum-based drugs. We present herein the synthesis and characterization of half-sandwich ruthenium compounds formulated as [Ru(p-cymene)(L)Cl][CF3SO3] (L = 1,1-bis(methylenediphenylphosphano)ethylene, 1; L = 1,1-bis(diphenylphosphano)ethylene, 2),… read more here.
Keywords: sandwich cymene; half; cymene compounds; half sandwich ... See more keywords