Synthesis, characterization and crystal structures of half-sandwich ruthenium complexes with bidentate chiral Schiff-base ligands
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2020.121129
Abstract: Abstract Condensation of salicylaldehyde or 5-nitrosalicylaldehyde with (S)-(+)-2-amino-3-methyl-1-butanol in refluxing ethanol afforded the chiral Schiff-base ligands (S)-N-(1-hydroxymethylisobutyl)salicylidene (HL1*) and (S)-N-1-hydroxymethylisobutyl-5-nitrosalicylidene (HL2*), respectively. Similarly, reaction of 3,5-di-tert-butylsalicylaldehyde or 3,5-dibromosalicylaldehyde with (R)-(+)-α-methylbenzylamine gave the chiral Schiff base… read more here.
Keywords: base ligands; chiral schiff; sandwich ruthenium; half sandwich ... See more keywords
In vitro and in vivo antitumor activity of novel half-sandwich ruthenium complexes containing quinoline derivative ligands.
Sign Up to like & getrecommendations! Published in 2023 at "Dalton transactions"
DOI: 10.1039/d2dt03317h
Abstract: A series of half-sandwich ruthenium complexes containing quinoline derivative ligands was synthesized, which had excellent antitumor toxicity toward a variety of cell lines and could localize lysosomes. The damage of lysosomes promotes the release of… read more here.
Keywords: ruthenium complexes; containing quinoline; half sandwich; sandwich ruthenium ... See more keywords
Half-sandwich ruthenium(II)-arene complexes: synthesis, spectroscopic studies, biological properties, and molecular modeling
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Coordination Chemistry"
DOI: 10.1080/00958972.2018.1553298
Abstract: Abstract In search for antitumor metal-based drugs that would mitigate the severe side-effects of cisplatin, Ru(II) complexes are gaining increasing recent interest. In this work, we report on the synthesis, characterization (1H- and 13C-NMR, FT-IR),… read more here.
Keywords: half; sandwich ruthenium; half sandwich; arene complexes ... See more keywords