Microwave-Mediated Site-Selective Heating of Spherical-Carbon-Bead-Supported Platinum for the Continuous, Efficient Catalytic Dehydrogenative Aromatization of Saturated Cyclic Hydrocarbons
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DOI: 10.1021/acssuschemeng.8b04655
Abstract: A microwave (MW)-assisted method for the continuous production of hydrogen from methylcyclohexane using platinum on spherical carbon beads has been developed, and its application to the efficient dehydrogenative aromatization of fully saturated cyclic alkanes, including… read more here.
Keywords: dehydrogenative aromatization; spherical carbon; site; saturated cyclic ... See more keywords
Site- and Enantiodifferentiating C(sp3)-H Oxidation Enables Asymmetric Access to Structurally and Stereochemically Diverse Saturated Cyclic Ethers.
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DOI: 10.1021/jacs.0c09636
Abstract: A manganese-catalyzed site- and enantiodifferentiating oxidation of C(sp3)-H bonds in saturated cyclic ethers has been described. The mild and practical method is applicable to a range of tetrahydrofurans, tetrahydropyrans, and medium-sized cyclic ethers with multiple… read more here.
Keywords: saturated cyclic; cyclic ethers; site enantiodifferentiating; site ... See more keywords