Six-Membered Saturated NHC-Stabilized Borenium Cations: Isolation of a Cationic Analogue of Borinic Acid.
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DOI: 10.1021/acs.inorgchem.2c00611
Abstract: The reaction of six-membered saturated NHC [1,3-di(2,6-diisopropylphenyl) tetrahydropyrimidine-2-ylidene; henceforth abbreviated as 6-SIDipp] with PhBCl2 yields a Lewis base adduct, 6-SIDipp·PhBCl2 (1), which readily undergoes nucleophilic substitution reaction with AgNO3, leading to the single (2) and… read more here.
Keywords: saturated nhc; borenium; acid; six membered ... See more keywords