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Published in 2024 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202409274
Abstract: Rare earth elements (REEs) are vital in high‐tech industries and defense due to their strategic significance. Crafting an efficient membranes channel for REE separation poses a significant challenge. Employing 2‐methylimidazole‐hydrolyzed OH−, dopamine polymerization is initiated…
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Keywords:
separation;
synergistic nanoarchitectonics;
rare earth;
nanoarchitectonics precision ... See more keywords
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Published in 2025 at "Advanced Materials"
DOI: 10.1002/adma.202412071
Abstract: Inserting metal ions into the porphyrin ring is one of the primary strategies to enhance the properties of porphyrin‐based metal–organic frameworks (MOFs). However, the straightforward, rapid, and energy‐efficient synthesis of porphyrin‐based MOFs with high metallization…
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Keywords:
synthesis scandium;
metalloporphyrin frameworks;
synthesis;
scandium metalloporphyrin ... See more keywords
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Published in 2019 at "Journal of Sustainable Metallurgy"
DOI: 10.1007/s40831-019-00210-4
Abstract: Bauxite residues, i.e., red mud, can be processed to recover various valuable end products, while reducing the environmental impact of the waste. Scandium is one of the valuable elements in bauxite residues. It is possible…
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Keywords:
crystallization techniques;
strip liquor;
crystallization;
scandium ... See more keywords
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Published in 2017 at "Chemosphere"
DOI: 10.1016/j.chemosphere.2017.02.083
Abstract: D201 resin and P507 extractant diluted with sulfonated kerosene were used to respectively separate vanadium and scandium, and impurity ions from hydrochloric acid leaching solution of red mud. More than 99% of vanadium was selectively…
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Keywords:
acid leaching;
leaching solution;
solution;
hydrochloric acid ... See more keywords
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Published in 2020 at "Hydrometallurgy"
DOI: 10.1016/j.hydromet.2019.105194
Abstract: Abstract Laterite ores account for >60% of the world's nickel resources. This ore contains considerable amount of scandium, a strategic material in increasingly high demand in various industries. Here, an innovative two-step process was developed…
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Keywords:
naoh cracking;
process;
scandium;
innovative process ... See more keywords
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Published in 2019 at "Minerals Engineering"
DOI: 10.1016/j.mineng.2018.11.052
Abstract: Abstract A study was carried out for recovery of scandium from KOH sub-molten salt (SMS) leaching cake of fergusonite. Major metals in the cake were rare earths (RE), K, Th, U and Ca, and minor…
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Keywords:
leaching cake;
scandium koh;
cake;
recovery scandium ... See more keywords
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Published in 2021 at "Separation and Purification Technology"
DOI: 10.1016/j.seppur.2021.119798
Abstract: Abstract The separation of scandium from the solution generated in acid leaching is one of the main challenges for the hydrometallurgical processing of bauxite residue. Several organic extractants were evaluated, being the most prominent phosphine…
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Keywords:
selective separation;
separation;
bauxite residue;
scandium ... See more keywords
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Published in 2017 at "Journal of Rare Earths"
DOI: 10.1016/s1002-0721(17)60992-x
Abstract: Abstract Experimental results here can give some new insights into the mechanism of selective recovery of scandium and sodium from high alkali Bayer red mud (RM) through sulfation-roasting-leaching process. Effects of roasting and leaching conditions…
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Keywords:
high alkali;
red mud;
bayer red;
scandium ... See more keywords
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Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c03565
Abstract: Two polymorphs of lithium-scandium sulfate hydrate LiSc(SO4)2·2H2O are isolated by chimie douce crystallization. Neutron- and X-ray powder diffraction data unveil their monoclinic shape (sp.gr. C2/c, m109-LSS) and orthorhombic lattices (sp.gr. P212121, o-LSS). An elevated temperature…
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Keywords:
temperature induced;
so4 2h2o;
lisc so4;
scandium ... See more keywords
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Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.8b00573
Abstract: We report the successful synthesis of three new Ruddlesden-Popper-type scandium oxychloride perovskites, Sr2ScO3Cl, Sr3Sc2O5Cl2, and Ba3Sc2O5Cl2, by conventional solid-state reaction. Small single crystals of Sr2ScO3Cl were obtained by a self-flux method, and the crystal structure…
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Keywords:
crystal structure;
sr3sc2o5cl2 ba3sc2o5cl2;
geometry;
scandium ... See more keywords
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Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c15046
Abstract: Polymers with rigid three-dimensional architectures have attracted significant attention due to their high rigidity and intrinsic microporosity. Here, we report the synthesis of a new class of rigid stepladder polymers featuring unique spirodihydroquinoline skeletons. Under…
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Keywords:
polyspiroannulation quinoline;
rigid stepladder;
scandium;
stepladder polymers ... See more keywords