Scandium catalysed stereoselective thio-allylation of allenyl-imidates.
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DOI: 10.1039/c9cc04302k
Abstract: The site-selective thio-allylation of electron-deficient 1,2-dienes is documented under scandium catalysis. The methodology enables the realization of α-β unsaturated, β-thio, γ-allyl carboxylic acid derivatives via a one-pot Lewis acid promoted Michael addition/[3,3]-sigmatropic rearrangement sequence (20… read more here.
Keywords: scandium catalysed; stereoselective thio; thio; catalysed stereoselective ... See more keywords