Synthesis, characterization and electrochemical properties of diiron azadithiolate complexes Fe2[(μ-SCH2)2NCH2CCH](CO)5L (L = CO or monophosphines)
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DOI: 10.1016/j.poly.2020.115007
Abstract: Abstract Diiron azadithiolate complexes are considered as important biomimetic models for the diiron subsite of [FeFe]-hydrogenases. Here, the diiron azadithiolate complex Fe2[(μ-SCH2)2NCH2CCH](CO)6 (1), produced by the condensation reaction of Fe2(μ-SCH2OH)2(CO)6 and NH2CH2CCH, is described. Meanwhile,… read more here.
Keywords: diiron azadithiolate; azadithiolate complexes; azadithiolate; complexes fe2 ... See more keywords