Coordination chemistry of thioether-carboranes in polynuclear metal carbonyl cluster complexes. B-H activation of thioether-carboranes by dirhenium carbonyl complexes
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.09.004
Abstract: Abstract Two new dirhenium compounds Re2(CO)8[μ-η2-1,3-C2B10H10(1-SCH3)](μ-H), 1 (3.2 % yield) and Re2(CO)8[μ-η2-1,4-C2B10H10(1-SCH3)](μ-H), 2 (31 % yield) were obtained from the reaction of closo-o-(1-SCH3)C2B10H11 with Re2(CO)8[μ-η2-C(H)C(H)Bun](μ-H) in an octane solution heated to reflux. Both compounds contain… read more here.
Keywords: re2; thioether carboranes; chemistry; sch3 ... See more keywords
Quantitative Account of the Bonding Properties of a Rubredoxin Model Complex [Fe(SCH3)4]q, q = -2, -1, +2, +3.
Sign Up to like & getrecommendations! Published in 2021 at "Journal of chemical theory and computation"
DOI: 10.1021/acs.jctc.1c00485
Abstract: Iron-sulfur clusters play important roles in biology as parts of electron-transfer chains and catalytic cofactors. Here, we report a detailed computational analysis of a structural model of the simplest natural iron-sulfur cluster of rubredoxin and… read more here.
Keywords: bonding properties; sch3 complexes; bond; quantitative account ... See more keywords
Structural evolution and ligand effects of (Au1L2)n, (Au2L3)n, and (Au3L4)n [n = 1–3, L = SCH3,P(CH3)2,PH2,Cl] clusters
Sign Up to like & getrecommendations! Published in 2019 at "Molecular Simulation"
DOI: 10.1080/08927022.2019.1630736
Abstract: ABSTRACT In this paper, we present a density-functional theory with a particle swarm optimisation algorithm to research the progress of the ligand effects of the gold (Au) structures and growth process of the [Au1L2]n, [Au2L3]n… read more here.
Keywords: ch3; ligand effects; sch3; ligand ... See more keywords