On the Magnetic Coupling and Spin Crossover Behavior in Complexes Containing the Head-to-Tail [FeII2(μ-SCN)2] Bridging Unit: A Magnetostructural Experimental and Theoretical Study.
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DOI: 10.1021/acs.inorgchem.7b03082
Abstract: A new dinuclear complex [{Fe(tpc-OBn)(NCS)(μ-NCS)}2] (1) based on the tripodal tpc-OBn ligand (tpc-OBn = tris(2-pyridyl)benzyloxymethane), containing bridging μ-κN:κS-SCN and terminal κN-SCN thiocyanate ligands, has been prepared and characterized by single crystal X-ray diffraction, magnetic studies,… read more here.
Keywords: magnetic coupling; scn bridging; spin crossover; head tail ... See more keywords