Two-Step Spin Crossover in Hofmann-Type Coordination Polymers [Fe(2-phenylpyrazine)2{M(CN)2}2] (M = Ag, Au).
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DOI: 10.1021/acs.inorgchem.1c03302
Abstract: Two 2D Hofmann-type complexes of the composition [Fe(Phpz)2{M(CN)2}2] (where Phpz = 2-phenylpyrazine; M = Ag, Au) have been synthesized, and their spin-crossover (SCO) behavior has been thoroughly characterized. Single-crystal X-ray analysis reveals that these complexes… read more here.
Keywords: sco behavior; hofmann type; two step; spin crossover ... See more keywords