Structures and properties of five metal–organic frameworks based on 3,3′,5,5′-azoxybenzenetetracarboxylic acid and different secondary building units
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2017.11.048
Abstract: Abstract Five new metal–organic frameworks (MOFs), named [Zn 2 (aobtc)(H 2 O) 4 ] ( 1 ), [Mn 3 (Haobtc) 2 (DMA) 2 (H 2 O) 2 ]·2H 2 O ( 2 ), [Co 3… read more here.
Keywords: azoxybenzenetetracarboxylic acid; secondary building; building units; metal organic ... See more keywords
Metallo-supramolecular assemblies of dinuclear Zn(II) and Mn(II) secondary building units (SBUs) and a bent silicon dicarboxylate ligand
Sign Up to like & getrecommendations! Published in 2018 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2018.08.027
Abstract: Abstract Two metallo-supramolecular polymers {[Zn2(L)4(DMF)2]·0.8DMF}n (1) and {[Mn2L2(DMSO)4]·2DMSO}n (2) (H2L = bis(p-carboxyphenyl)diphenylsilane) have been synthetized by the reaction of Zn(NO3)2·6H2O and Mn(NO3)2·4H2O respectively, with the above mentioned acid as ligand under solvothermal conditions. Both coordination polymers were… read more here.
Keywords: supramolecular assemblies; secondary building; metallo supramolecular; dinuclear secondary ... See more keywords
Pre-synthesized secondary building units in the rational synthesis of porous coordination polymers
Sign Up to like & getrecommendations! Published in 2017 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2017.07.001
Abstract: The tailored synthesis of periodic coordination structures is fundamentally important for the design of porous compounds with desired functionalities. The building block approach allows a rational and modular design of metal-organic frameworks to be accomplished… read more here.
Keywords: coordination; secondary building; building units; synthesized secondary ... See more keywords
Solvent-Effected Coordination Variation of Flexible Ligands to Cu(II) for the Formation of 1D and 2D Secondary Building Units for Metal-Organic Frameworks.
Sign Up to like & getrecommendations! Published in 2021 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.1c00361
Abstract: Producing more than one structure from the same set of metal and ligand precursors will grant structural diversity in metal-organic framework (MOF) systems. One of the biggest obstacles of getting structural diversity for the late… read more here.
Keywords: coordination; secondary building; flexible ligands; building units ... See more keywords
A Microporous Metal-Organic Framework Incorporating Both Primary and Secondary Building Units for Splitting Alkane Isomers.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.1c12068
Abstract: We demonstrate the assembly of a mononuclear metal center, a hexanuclear cluster, and a V-shaped, trapezoidal tetracarboxylate linker into a microporous metal-organic framework featuring an unprecedented 3-nodal (4,4,8)-c lyu topology. The compound, HIAM-302, represents the… read more here.
Keywords: secondary building; metal organic; microporous metal; metal ... See more keywords
Nickel(II) metal–organic frameworks with N,N′-di(4-pyridyl)-naphthalenediimide ligands: influence of secondary building unit geometry on dimensionality and framework dimensions
Sign Up to like & getrecommendations! Published in 2017 at "CrystEngComm"
DOI: 10.1039/c7ce00956a
Abstract: When Ni(NO3)2·6H2O and N,N′-di(4-pyridyl)-1,4,5,8-naphthalenetetracarboxydiimide (DPNDI) are reacted, a one-dimensional coordination polymer (1) is formed. However, analogous reactions with either terephthalic acid (2) or 2,6-naphthalenedicarboxylic acid (3) and DPNDI affords two-dimensional, pillared metal–organic frameworks. 2 and… read more here.
Keywords: building unit; secondary building; metal organic; geometry ... See more keywords
A Zn(ii) metal-organic framework with dinuclear [Zn2(N-oxide)2] secondary building units.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c8dt04879g
Abstract: We report the synthesis, structural characterisation, and adsorption properties of a three-dimensional metal-organic framework [Zn(pydcao)(DMF)] (H2-pydcao = 3,5-pyridinedicarboxylic acid N-oxide) that has an unprecedented [Zn2(N-oxide)2] secondary building unit. read more here.
Keywords: secondary building; oxide secondary; metal organic; zn2 oxide ... See more keywords
Metal removal from the secondary building unit of bio-MOF-1 by adenine N6-alkylation while retaining the overall 3D porous topology
Sign Up to like & getrecommendations! Published in 2020 at "CrystEngComm"
DOI: 10.1039/d0ce00631a
Abstract: A novel approach to modify the SBU of the well-known bio-MOF-1 by reducing the nuclearity of the metal cluster while retaining the topology of the anionic 3D framework is reported. The resulting BioMOF is prone… read more here.
Keywords: secondary building; metal removal; topology; removal secondary ... See more keywords
Cyclic [Cu-biRadical]2 Secondary Building Unit in 2p-3d and 2p-3d-4f Complexes: Crystal Structure and Magnetic Properties
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28062514
Abstract: Employing the new nitronyl nitroxide biradical ligand biNIT-3Py-5-Ph (2-(5-phenyl-3-pyridyl)-bis(4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide)), a 16-spin Cu-radical complex, [Cu8(biNIT-3Py-5-Ph)4(hfac)16] 1, and three 2p-3d-4f chain complexes, {[Ln(hfac)3][Cu(hfac)2]2(biNIT-3Py-5-Ph)2}n (LnⅢ= Gd 2, Tb 3, Dy 4; hfac = hexafluoroacetylacetonate), have been prepared and… read more here.
Keywords: building unit; secondary building; binit 3py;